منابع مشابه
Bis(dicyclohexylphosphino)ethane. Structures of [RuH(dcpe)2]+[BPh4]- and of the Zwitterionic {(η6-C6H5)BPh3}RuH(dcpe)
Two hydrido ruthenium complexes could be isolated from the reaction between RuCl2(DMSO)4 (DMSO ) dimethyl sulfoxide) and the chelating 1,2-bis(dicyclohexylphosphino)ethane (dcpe) and [BPh4]. These are [RuH(dcpe)2][BPh4] with a five-coordinate, 16 valence electron cation and the neutral zwitterionic 18 valence electron compound {(η-C6H5)BPh3}RuH(dcpe). The relative amounts of these products depe...
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Correspondence Address/Yazışma Adresi Dr. Nurhan Fıstıkcı, Bakırköy Prof. Dr. Mazhar Osman Ruh Sağlığı ve Sinir Hastalıkları Eğitim ve Araştırma Hastanesi, Psikiyatri Kliniği, İstanbul, Türkiye Phone: +90 533 526 13 66 E-mail: [email protected] Received/Geliş tarihi: 19.06.2014 Accepted/Kabul tarihi: 22.06.2014 ©Copyright 2014 by Turkish Association of Neuropsychiatry / ©Telif Hakkı 2014...
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متن کاملSynthesis and reactivity of ruthenium tridentate bis-phosphinite ligand complexes.
The tridentate ligands E(CH2CH2OPiPr2)2 (E = NH 1, E = S 2) were employed in the synthesis of a number of ruthenium complexes. Reaction of these ligands with (Ph3P)3RuCl2 afforded the dimers [Ru(HN(CH2CH2OPiPr2)2)Cl(μ-Cl)]2 (3) and [(Ru(E(CH2CH2OPiPr2)2))2(μ-Cl)3][X] (E = NH, X = PF64, E = S, X = Cl 5), respectively. Using (Ph3P)3RuHCl in reactions with 1 gave Ru(NH(CH2CH2OPiPr2)2)(PPh3)HCl (6)...
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ژورنال
عنوان ژورنال: Kriz Dergisi
سال: 2004
ISSN: 1300-980X
DOI: 10.1501/0000781